By P. P. Ewald
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Extra info for 50 Years of X-ray Diffraction
Page 1 of 8 pages Paper 7 - Dalbe 30-31March 2011-Cologne, Germany Silicone Elastomers 2011 Nexans has developed a new generation of light, compact silicone cables which can operate in temperatures from -45° C to 150° C. For high-voltage machines, transformers, motors and generators, where high temperatures prevail and flexibility is required, Nexans developed silicone cables with good abrasion resistance and high tear-resistant performance. These cables are lighter and more flexible than traditional rubber cables and will endure higher temperatures.
HC Extrude Shock Heat > 450° C Heating Tunnel 2 – 10 m > 250°C Picture 4: Principle of Silicone extrusion with heat Additionally, the UV system can provide processing advantages of extrusion without heat and minimal shrinkage in the final part. In addition, the shape of the extruded parts have shown an excellent dimensional stability in applications like thick round tubes and complicated profiles. UV Source ~ 30cm Picture 5: Principle of Silicone Extrusion with UV Light These materials are currently available as transparent and colored custom compounds providing potentially cost effective solutions to demanding extrusion applications in the consumer, industrial and healthcare industries.
Figure 2 shows the storage modulus and complex viscosity of the LLDPE-PDMS rubber blends at 180°C. The results clearly indicate that the neat polymer blends exhibit shear thinning behaviour similar to the pristine polymers and remain intermediate to those of the neat LLDPE and PDMS rubber. Storage modulus (G′) of the blends increases with increase in angular frequency, because of the molecular entanglements which do not get enough time to slip and relax on application of stress. Also that higher viscosity of PDMS rubber which remains in the dispersed state in the LLDPE continuous matrix contributes to higher modulus.
50 Years of X-ray Diffraction by P. P. Ewald